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Advantageous mechanochemical synthesis of copper(I) selenide semiconductor, characterization, and properties

《化学科学与工程前沿（英文）》 2022年 第16卷 第3期   页码 433-442 doi: 10.1007/s11705-021-2066-6

摘要： Copper(I) selenide-nanocrystalline semiconductor was synthesized via one-step mechanochemical synthesis after 5 min milling in a planetary ball mill. The kinetics of synthesis was followed by X-ray powder diffraction analysis and specific surface area measurements of milled 2Cu/Se mixtures. The X-ray diffraction confirmed the orthorhombic crystal structure of Cu2Se with the crystallite size ~25 nm. The surface chemical structure was studied by X-ray photoelectron spectroscopy, whereby the binding energy of the Cu 2p and Se 3d signals corresponded to Cu+ and Se2– oxidation states. Transmission electron microscopy revealed agglomerated nanocrystals and confirmed their orthorhombic structure, as well. The optical properties were studied utilizing ultraviolet-visible spectroscopy and photoluminescence spectroscopy. The direct bandgap energy 3.7 eV indicated a blue-shift phenomenon due to the quantum size effect. This type of Cu2Se synthesis can be easily adapted to production dimensions using an industrial vibratory mill. The advantages of mechanochemical synthesis represent the potential for inexpensive, environmentally-friendly, and waste-free manufacturing of Cu2Se.

关键词： Cu2Se     berzelianite     nanocrystalline semiconductor     mechanochemical synthesis     planetary ball mill    

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Structural and optical properties of nanostructured copper sulfide semiconductor synthesized in an industrial

Marcela Achimovičová, Erika Dutková, Erika Tóthová, Zdenka Bujňáková, Jaroslav Briančin, Satoshi Kitazono

《化学科学与工程前沿（英文）》 2019年 第13卷 第1期   页码 164-170 doi: 10.1007/s11705-018-1755-2

摘要：

Chalcogenide nanostructured semiconductor, copper sulfide (CuS) was prepared from copper and sulfur powders in stoichiometric ratio by a simple, fast, and convenient one-step mechanochemical synthesis after 40 min of milling in an industrial eccentric vibratory mill. The kinetics of the mechanochemical synthesis and the influence of the physical properties of two Cu powder precursor types on the kinetics were studied. The crystal structure, physical properties, and morphology of the product were characterized by X-ray diffraction (XRD), the specific surface area measurements, particle size distribution and scanning electron microscopy. The XRD analysis confirmed the hexagonal crystal structure of the product-CuS (covellite) with the average size of the crystallites 11 nm. The scanning electron microscopy analysis has revealed that the agglomerated grains have a plate-like structure composed of CuS nanoparticles. The thermal analysis was performed to investigate the thermal stability of the mechanochemically synthesized CuS. The optical properties were studied using UV-Vis and photoluminescence spectroscopy. The determined optical band gap energy 1.80 eV responds to the value of the bulk CuS, because of agglomerated nanoparticles. In addition, a mechanism of CuS mechanochemical reaction was proposed, and the verification of CuS commercial production was performed.

关键词： copper sulfide     industrial mechanochemical synthesis     thermal analysis     optical properties    

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Enhancing the adsorption function of biochar by mechanochemical graphitization for organic pollutant

《环境科学与工程前沿（英文）》 2021年 第15卷 第6期 doi: 10.1007/s11783-021-1418-2

摘要：

• Mechanochemical treatment reduced the calcination temperature for biochar synthesis.

关键词： Biochar     Mechanochemical treatment     Graphitization     Calcination temperature     Organic pollutant    

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Solvent-free mechanochemical mild oxidation method to enhance adsorption properties of chitosan

《环境科学与工程前沿（英文）》 2021年 第15卷 第6期 doi: 10.1007/s11783-021-1416-4

摘要：

• Solvent-free chitosan oxidation is obtained by rapid mechanochemical reaction.

关键词： Chitosan     High energy ball milling     Mechanochemistry     Oxidation    

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Modified iron-molybdate catalysts with various metal oxides by a mechanochemical method: enhanced formaldehyde

Xue Liu, Lingtao Kong, Shengtao Xu, Chaofan Liu, Fengyun Ma

《化学科学与工程前沿（英文）》 2021年 第15卷 第5期   页码 1099-1110 doi: 10.1007/s11705-020-2008-8

摘要： A mechanochemical method was employed to prepare modified iron molybdate catalysts with various metal salts as precursors. The physicochemical properties of the iron molybdate catalysts were characterized, and their performances in catalyzing the reaction from methanol to formaldehyde (HCHO) were evaluated. Iron molybdate catalysts doped with Co(NO ) ·6H O and Al(NO ) ·9H O resulted in high HCHO yields. Compared with a commercial catalyst, the HCHO yields in the reaction with the modified catalyst at an optimal Co/Mo molar ratio reached 97.37%. According to chemical state analysis, the formation of CoO and the efficient decrease in the MoO sublimation rate could be important factors enhancing the HCHO yield in reactions catalyzed with iron molybdate doped with different Co/Mo mole ratios.

关键词： iron molybdate catalyst     metal oxides     methanol to formaldehyde     Co/Mo ratio     formaldehyde yield    

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Synthesis, characterization and hydrotreating performance of supported tungsten phosphide catalysts

SUN Guida, LI Cuiqing, ZHOU Zhijun, LI Fengyan

《化学科学与工程前沿（英文）》 2008年 第2卷 第2期   页码 155-164 doi: 10.1007/s11705-008-0038-8

摘要： Supported tungsten phosphide catalysts were prepared by temperature-programmed reduction of their precursors (supported phospho-tungstate catalysts) in H and characterized by X-ray diffraction (XRD), BET, temperature-programmed desorption of ammonia (NH-TPD) and X-ray photoelectron spectroscopy (XPS). The reduction-phosphiding processes of the precursors were investigated by thermogravimetry and differential thermal analysis (TG-DTA) and the suitable phosphiding temperatures were defined. The hydrodesulfurization (HDS) and hydrodenitrogenation (HDN) activities of the catalysts were tested by using thiophene, pyridine, dibenzothiophene, carbazole and diesel oil as the feedstock. The TiO, -AlO supports and the Ni, Co promoters could remarkably increase and stabilize active W species on the catalyst surface. A suitable amount of Ni (3%–5%), Co (5%–7%) and V (1%–3%) could increase dispersivity of the W species and the BET surface area of the WP/-AlO catalyst. The WP/-AlO catalyst possesses much higher thiophene HDS and carbazole HDN activities and the WP/TiO catalyst has much higher dibenzothiophene (DBT) HDS and pyridine HDN activities. The Ni, Co and V can obviously promote the HDS activity and inhibit the HDN activity of the WP/-AlO catalyst. The G-Ni5 catalyst possesses a much higher diesel oil HDS activity than the sulphided industrial NiW/-AlO catalyst. In general, a support or promoter in the WP/-AlO catalyst which can increase the amount and dispersivity of the active W species can promote its HDS and HDN activities.

关键词： tungsten phosphide     differential thermal     catalyst surface     industrial NiW/-AlO     general    

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Synthesis and characterization of magnesium hydroxide by batch reaction crystallization

Xingfu SONG, Shuying SUN, Dengke ZHANG, Jin WANG, Jianguo YU

《化学科学与工程前沿（英文）》 2011年 第5卷 第4期   页码 416-421 doi: 10.1007/s11705-011-1125-9

摘要： Magnesium hydroxide with high purity and uniform particle size distribution was synthesized by the direct precipitation method using MgCl and NaOH as reactive materials and NaCl as additive to improve the crystallization behavior of the product. The particle size distribution, crystal phase, morphology, and surface area of magnesium hydroxide were characterized by Malvern laser particle size analyzer, X-ray diffraction (XRD), scanning electron microscope (SEM) and Branauer-Emmett-Teller (BET) method, respectively. The purity of products was analyzed by the chemical method. The effects of synthesis conditions on the particle size distribution and water content (filtration cake) of magnesium hydroxide were investigated. The results indicated that feeding mode and rate, and reaction temperature had important effects on water content and the particle size distribution of the product, and sodium chloride improved the crystallization behavior of magnesium hydroxide. The ball-like magnesium hydroxides with the particle size distribution of 6.0–30.0 μm and purity higher than 99.0% were obtained. This simple and mild synthesis method was promising to be scaled up for the industrial production of magnesium hydroxide.

关键词： magnesium hydroxide     direct precipitation method     industrial crystallization     particle size distribution    

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Conservation and adaptive reuse of industrial heritage in Shanghai

ZHANG Song

《结构与土木工程前沿（英文）》 2007年 第1卷 第4期   页码 481-490 doi: 10.1007/s11709-007-0065-4

摘要： This paper takes a retrospective review of the evolution of the conservation of industrial heritage in urban Shanghai since the 1990s within the context of the international industrial heritage conservation movement, with the emph

关键词： evolution     industrial     international industrial     retrospective     Shanghai    

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Conservation and adaptive-reuse of historical industrial building in China in the post-industrial era

WANG Jianguo, JIANG Nan

《结构与土木工程前沿（英文）》 2007年 第1卷 第4期   页码 474-480 doi: 10.1007/s11709-007-0064-5

摘要： The conservation and adaptive-reuse of historical industrial building is one of the most important issues to be solved in today s urban development and construction in China. In this paper, the necessity and academic meaning of the conservation and adaptive-reuse of historical industrial building were discussed by reviewing its development rend both at home and abroad, and the basic contents of the implementation of the conservation and adaptive-reuse of historical industrial building in China with specific cases provided were analyzed. It is the central task for China to put forward the restructuring and design methods, assessment principles and relevant core technical specifications based on the empirical researches on the historical industrial building and site.

关键词： historical industrial     industrial building     implementation     adaptive-reuse     empirical    

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Can industrial intelligence promote industrial transformation? ––Case of mining enterprises

Anlin SHAO

《工程管理前沿（英文）》 2017年 第4卷 第3期   页码 375-378 doi: 10.15302/J-FEM-2017108

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Industrial water treatment and industrial marine outfalls: Achieving the right balance

Adrian W. K. Law,Chunyan Tang

《化学科学与工程前沿（英文）》 2016年 第10卷 第4期   页码 472-479 doi: 10.1007/s11705-016-1592-0

摘要： Industrial water treatment and industrial marine outfalls both function together to reduce the pollutant concentrations in the effluent and mitigate the potential impact on the environment. The former uses environmental treatment technology with energy and material cost considerations, while the latter utilizes the natural assimilation potential of the coastal water environment achievable at the outfall location. Because of their synergistic nature, marine outfalls are now commonly used for the disposal of partially treated domestic and industrial effluents in many coastal cities around the world, with many successful examples of low and acceptable risks to the environment. The objective of this paper is to review their balance from both environmental and economic considerations. We also discuss the end-of-the-pipe and mixing zone approaches for industrial effluents, and give some recommendations particularly for developing countries. Finally, we emphasize that a compulsory and vigorous monitoring program is essential regardless of how the balance is achieved.

关键词： industrial effluent treatment     industrial marine outfalls     economic and environmental considerations    

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Automated synthesis of steady-state continuous processes using reinforcement learning

《化学科学与工程前沿（英文）》 2022年 第16卷 第2期   页码 288-302 doi: 10.1007/s11705-021-2055-9

摘要： Automated flowsheet synthesis is an important field in computer-aided process engineering. The present work demonstrates how reinforcement learning can be used for automated flowsheet synthesis without any heuristics or prior knowledge of conceptual design. The environment consists of a steady-state flowsheet simulator that contains all physical knowledge. An agent is trained to take discrete actions and sequentially build up flowsheets that solve a given process problem. A novel method named SynGameZero is developed to ensure good exploration schemes in the complex problem. Therein, flowsheet synthesis is modelled as a game of two competing players. The agent plays this game against itself during training and consists of an artificial neural network and a tree search for forward planning. The method is applied successfully to a reaction-distillation process in a quaternary system.

关键词： automated process synthesis     flowsheet synthesis     artificial intelligence     machine learning     reinforcement learning    

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Industrial solid waste flow analysis of eco-industrial parks: implications for sustainable waste management

Yongpeng Lü, Kai YANG, Yue CHE, Zhaoyi SHANG, Jun TAI, Yun JIAN

《环境科学与工程前沿（英文）》 2012年 第6卷 第4期   页码 575-587 doi: 10.1007/s11783-011-0344-0

摘要： Sustainable waste management in the industrial ecology perspective brings enormous challenges to the existing methodology of waste analysis at the industrial park (IP) scale. In this study, a four-step method was proposed for industrial solid waste (ISW) flow analysis of eco-industrial parks (EIPs) and applied to two IPs in eastern China. According to a park-wide census of 619 industrial enterprises and 105 questionnaires by a survey from 2006 to 2008, the results indicated that: 1) at the enterprise scale, more than 60% of enterprises were small-ISW-generation enterprises which encountered great difficulties on effective waste management; 2) at the IP scale, though the two IPs have set up their own environmental management systems and passed the ISO 14001 certification, the efficiencies of the ISW management systems have yet to be improved in the industrial ecology perspective; and 3) at the regional scale, more than 97% of ISW flowed within the provincial region, indicating that the provincial governments prevented the wastes from flowing into their own “back yard”. Effective waste management should be placed in a broader perspective. Approaches to sustainable waste management may include wastes exchange, efficient waste and information flow, virtual EIP, waste minimization clubs and regionalization of waste management.

关键词： industrial solid waste     waste flow analysis     eco-industrial parks     sustainable waste management     “not in my back yard”    

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Forecasting industrial emissions: a monetary approach

Yang DONG, Yi LIU, Jining CHEN, Yebin DONG, Benliang QU

《环境科学与工程前沿（英文）》 2012年 第6卷 第5期   页码 734-742 doi: 10.1007/s11783-012-0451-6

摘要： Forecasts of industrial emissions provide a basis for impact assessment and development planning. To date, most studies have assumed that industrial emissions are simply coupled to production value at a given stage of technical progress. It has been argued that the monetary method tends to overestimate pollution loads because it is highly influenced by market prices and fails to address spatial development schemes. This article develops a land use-based environmental performance index (L-EPI) that treats the industrial land areas as a dependent variable for pollution emissions. The basic assumption of the method is that at a planning level, industrial land use change can represent the change in industrial structure and production yield. This physical metric provides a connection between the state-of-the-art and potential impacts of future development and thus avoids the intrinsic pitfalls of the industrial Gross Domestic Product-based approach. Both methods were applied to examine future industrial emissions at the planning area of Dalian Municipality, North-west China, under a development scheme provided by the urban master plan. The results suggested that the L-EPI method is highly reliable and applicable for the estimation and explanation of the spatial variation associated with industrial emissions.

关键词： industrial emissions     environmental performance index     spatial planning     industrial land use    

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Effect of potassium carbonate on catalytic synthesis of calcium carbide at moderate temperature

Dejun SHI, Ke QIAO, Zifeng YAN

《化学科学与工程前沿（英文）》 2011年 第5卷 第3期   页码 372-375 doi: 10.1007/s11705-010-0570-1

摘要： Calcium carbide was successfully synthesized by carbothermal reduction of lime with coke at 1973 K for 1.5 h. The effect of potassium carbonate as additive on the composition and morphology of the product was investigated using X-ray diffraction and scanning electron microscope. Addition of potassium carbonate increased the yield of calcium carbide. The sample in the presence of potassium carbonate generated acetylene gas of 168.3 L/kg, which was 10% higher than that in the absence of potassium carbonate. This result confirmed the catalytic effect of potassium carbonate on the synthesis of calcium carbide. A possible mechanism of the above effects was that the additive, which was melted at the reduction temperature, dissolved CaO and so promoted the contact between CaO and carbon, which was essential for the solid-solid reaction to form calcium carbide.

关键词： calcium carbide     synthesis     catalysis    

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标题 作者 时间 类型 操作

Advantageous mechanochemical synthesis of copper(I) selenide semiconductor, characterization, and properties

期刊论文

Structural and optical properties of nanostructured copper sulfide semiconductor synthesized in an industrial

Marcela Achimovičová, Erika Dutková, Erika Tóthová, Zdenka Bujňáková, Jaroslav Briančin, Satoshi Kitazono

期刊论文

Enhancing the adsorption function of biochar by mechanochemical graphitization for organic pollutant

期刊论文

Solvent-free mechanochemical mild oxidation method to enhance adsorption properties of chitosan

期刊论文

Modified iron-molybdate catalysts with various metal oxides by a mechanochemical method: enhanced formaldehyde

Xue Liu, Lingtao Kong, Shengtao Xu, Chaofan Liu, Fengyun Ma

期刊论文

Synthesis, characterization and hydrotreating performance of supported tungsten phosphide catalysts

SUN Guida, LI Cuiqing, ZHOU Zhijun, LI Fengyan

期刊论文

Synthesis and characterization of magnesium hydroxide by batch reaction crystallization

Xingfu SONG, Shuying SUN, Dengke ZHANG, Jin WANG, Jianguo YU

期刊论文

Conservation and adaptive reuse of industrial heritage in Shanghai

ZHANG Song

期刊论文

Conservation and adaptive-reuse of historical industrial building in China in the post-industrial era

WANG Jianguo, JIANG Nan

期刊论文

Can industrial intelligence promote industrial transformation? ––Case of mining enterprises

Anlin SHAO

期刊论文

Industrial water treatment and industrial marine outfalls: Achieving the right balance

Adrian W. K. Law,Chunyan Tang

期刊论文

Automated synthesis of steady-state continuous processes using reinforcement learning

期刊论文

Industrial solid waste flow analysis of eco-industrial parks: implications for sustainable waste management

Yongpeng Lü, Kai YANG, Yue CHE, Zhaoyi SHANG, Jun TAI, Yun JIAN

期刊论文

Forecasting industrial emissions: a monetary approach

Yang DONG, Yi LIU, Jining CHEN, Yebin DONG, Benliang QU

期刊论文

Effect of potassium carbonate on catalytic synthesis of calcium carbide at moderate temperature

Dejun SHI, Ke QIAO, Zifeng YAN

期刊论文